Olefin Metathesis Cycle

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Many laboratories have developed improved versions of the catalyst ever since, some of which are shown below.

The molybdenum based , which are based on ruthenium-benzylidene, are more user-friendly as they have great functional group tolerance and are easy to handle.

Studies on OM have further enhanced the understanding of this process, promoting the development of interesting and useful metathesis catalysts.

The generally accepted mechanism was originally proposed by Chauvin and Hérisson (Scheme 1) [15].

-The Grubbs catalyst is stable enough to be weighed in open air but once it is in a solution it is sensitive to the dissolved oxygen.

The use of degassed solvent is recommended to ensure high yield.Traditional methods of control in OM have relied on the intrinsic reactivity of an olefin, as well as thermodynamic selectivities, but recent developments in OM catalysts have allowed for tailoring of the catalytic scaffold to impart some stereochemical control on the olefinic products.Early stereoselective OM research focused on the desymmetrization of achiral olefins to provide chiral molecules through the alteration of the ligand scaffold [11,16,17].The metathesis catalysts have been influential in polymer chemistry too, thanks to their high functional group tolerance enabling the synthesis of polyfunctionalized polymers that had been difficult to synthesize.Likewise, a new class of polymers called has been explored using metathesis.One method that has found wide application in this endeavor is olefin metathesis (OM) [1,2,3,4,5,6,7,8].Initially viewed as a strange olefin rearrangement reaction [9,10], the utility of OM now ranges from synthetic organic chemistry [11,12] to materials chemistry [13,14].As understanding for the stereochemical arrangement of the metallacycle intermediate progressed, further variations were made in continual pursuit of one of the unmet challenges in OM: kinetic -selectivity [18,19,20].An incredible amount of effort has been devoted to these quests, which have opened the door to numerous discoveries. Wiley Online Library requires cookies for authentication and use of other site features; therefore, cookies must be enabled to browse the site.Detailed information on how Wiley uses cookies can be found in our Privacy Policy.


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